1.42 Non-stoichiometric cuprous oxide, Cu2O can be prepared in laboratory. In this oxide, copper to oxygen ratio is slightly less than 2:1. Can you account for the fact that this substance is a p-type semiconductor?

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1.42 The ratio less than 2:1 in Cu2O shows that some cuprous (Cu+) ions have been replaced by cupric (Cu+2) ions. To maintain electrical neutrality, every two Cu+ ions will be replaced by one Cu+2 ion, thereby creating a hole. As conduction will be due to the presence of these positive holes, hence

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Chemistry Ncert Solutions Class 12th 2023

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