10.10 Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides: (i) (CH3) 2CHCH(Cl)CH3 (ii) CH3CH2CH(CH3 )CH(C2H5 )Cl (iii) CH3CH2C(CH3 ) 2CH2 I (iv) (CH3 ) 3CCH2CH(Br)C6H5 (v) CH3CH(CH3 )CH(Br)CH3 (vi) CH3C(C2H5 ) 2CH2Br (vii) CH3C(Cl)(C2H5 )CH2CH3 (viii) CH3CH=C(Cl)CH2CH(CH3 ) 2 (ix) CH3CH=CHC(Br)(CH3 ) 2 (x) p-ClC6H4CH2CH(CH3 )2 (xi) m-ClCH2C6H4CH2C(CH3 )3 (xii) o-Br-C6H4CH(CH3 )CH2CH3
10.10 Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides: (i) (CH3) 2CHCH(Cl)CH3 (ii) CH3CH2CH(CH3 )CH(C2H5 )Cl (iii) CH3CH2C(CH3 ) 2CH2 I (iv) (CH3 ) 3CCH2CH(Br)C6H5 (v) CH3CH(CH3 )CH(Br)CH3 (vi) CH3C(C2H5 ) 2CH2Br (vii) CH3C(Cl)(C2H5 )CH2CH3 (viii) CH3CH=C(Cl)CH2CH(CH3 ) 2 (ix) CH3CH=CHC(Br)(CH3 ) 2 (x) p-ClC6H4CH2CH(CH3 )2 (xi) m-ClCH2C6H4CH2C(CH3 )3 (xii) o-Br-C6H4CH(CH3 )CH2CH3
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1 Answer
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(i) 2-chloro-3-methylbutane, (2? alkyl halide)
Explanation: The Cl atom is attached with two alkyl groups therefore 2? alkyl halide.
(ii) 3-chloro-4-methylhexane (2? alkyl halide)
Explanation: The Cl atom is attached with two alkyl groups therefore 2? alkyl halide.
(iii) 1-iodo-2,2-dimethylbutane (1? alkyl halide)
Explanation: The atom I is attached with one alkyl group therefore 1? alkyl halide.
(iv) 1-bromo-3,3-dimethyl-1-phenylbutane (2? benzylic halide)
Explanation: The atom Br is attached with two alkyl groups with the benzene group therefore 2? benzylic halide.
(v) 2-bromo-3-me
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