11.13.

  • Rationalise the given statements and give chemical reactions:
  • Lead (II) chloride reacts with Clto give PbCl4.
  • Lead (IV) chloride is highly unstable towards heat.
  • Lead is known not to form an iodide PbI4.

0 1 View | Posted 4 months ago
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    Answered by

    Vishal Baghel | Contributor-Level 10

    4 months ago
    • PbCl+ Cl2→ PbCl4.
      This is because Pb can show +2 oxidation state more easily than +4 due to inert pair effect.
    • PbCl4→ PbCl2 + Cl2
      Because Pb2+ is more stable than Pb4+ due to inert pair effect.
    • PbI4does not exist because I- ion being a powerful reducing agent reduces Pb4+ ion to Pb2+ ion in solution.

    Pb4+ + 2I → Pb2+ + I2

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