The difference in bond length is due to the difference in the state of hybridisation. In BF3 'B' is sp2 hybridised and in BF4– 'B' is sp3 hybridised.
<p>The difference in bond length is due to the difference in the state of hybridisation. In BF<sub>3</sub> 'B' is sp<sup>2</sup> hybridised and in BF<sub>4</sub><sup>–</sup> 'B' is sp<sup>3</sup> hybridised.</p>
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