In ortho nitrophenol there is intra-molecular H bonding, whereas in para-nitrophenol there is inter-molecular H bonding, as shown below:
And because of that para-nitrophenol get tightly bounded with water and ortho nitrophenol is steam volatile and it will leave the solution.
<p><strong>11.20 </strong></p><p>In ortho nitrophenol there is intra-molecular H bonding, whereas in para-nitrophenol there is inter-molecular H bonding, as shown below:</p><p>And because of that para-nitrophenol get tightly bounded with water and ortho nitrophenol is steam volatile and it will leave the solution.</p>
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