13.3 Account for the following:

(i) pKb of aniline is more than that of methylamine.

 

(ii) Ethylamine is soluble in water whereas aniline is not.

 

(iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide.

 

(iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.

 

(v) Aniline does not undergo Friedel-Crafts reaction.

 

(vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines.

 

(vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.