13.3 How will you convert

(i) Benzene into aniline

(ii) Benzene into N, N-dimethylaniline

(iii) Cl–(CH2)4–Cl into hexan-1,6-diamine?

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    Answered by

    Vishal Baghel | Contributor-Level 10

    5 months ago

    Benzene into aniline

    When Benzene is treated with HNO3/H2SO4 it forms nitrobenzene. When Nitrobenzene reduced with Sn/HCL it forms Aniline because Sn/HCl is a reducing Mixture.

    When Benzene is reacted with nitrating mixture it forms nitrobenzene. When it Reduced H2/Pd in ethanol or Sn/HCl, it forms Aniline. When Aniline reacts 2 times with CH3Cl It forms N, N- dimethylaniline.

    When 1,4-dichlorobutane reacts with NaCN it forms Di cyanide compound, After Hydrogenation it forms the Hexane 1,6-Diamine.

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Kindly consider the following figure

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