13.9 Convert
(i) 3-Methylaniline into 3-nitrotoluene.
(ii) Aniline into 1,3,5 – tribromobenzene.
13.9 Convert
(i) 3-Methylaniline into 3-nitrotoluene.
(ii) Aniline into 1,3,5 – tribromobenzene.
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1 Answer
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1- When 3-methylaniline treated with NaNO2 + HCl it gets converted into chlorine complex.
When that complex reacted with HBF4 It gets converted into Barium Fluoride complex. This complex reacts with NaNO2 in presence of copper to give 3-Nitrotoluene.
When aniline reacts with Br2 water it gets converted into 2,4,6 tribromobenzamine. When this further reacted with NaNO2/HCl it forms Chloride complex. This complex forms 1,3,5 tribromobenzene after treating with H3PO2 in presence of water.
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