14.18 Enumerate the reactions of D-glucose which cannot be explained by its open chain structure. 

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14.18

Open structure of D-glucose could not explain the following reactions:

(i) Despite having the aldehyde group, glucose does not give 2,4 DNP test and Schiff's

(ii) Glucose does not react with sodium hydrogen sulphite to form addition

(iii) The absence of free –CHO group is shown when the penta-a

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