4.13 The decomposition of dimethyl ether leads to the formation of CH4 , H2 and CO and the reaction rate is given by Rate = k [CH3OCH3 ] 3/2 The rate of reaction is followed by increase in pressure in a closed vessel, so the rate can also be expressed in terms of the partial pressure of dimethyl ether, i.e., Rate= k(PCH3OCH3)3/2 If the pressure is measured in bar and time in minutes, then what are the units of rate and rate constants? 

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    Payal Gupta | Contributor-Level 10

    5 months ago

    4.13 Rate of given chemical reaction will be represented as

    -d [pCH3OCH3] / dt

    Hence units of rate is bar min-1

    To find units of K, K = rate/ [pCH3OCH3]3/2

    The unit of k = bar -1/2min-1.

    Units of Rate- bar min-1. and Units of Rate constant K : bar -1/2min -1

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