4.17 In a pseudo first order hydrolysis of ester in water, the following results were obtained, Calculate the average rate of reaction between the time intervals 30 to 60 seconds.

t/s

0

30

60

90

[Ester]/mol L-1

0.55

0.31

0.17

 0.085

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8 months ago

4.17  (i) Average rate of reaction over interval is [change in concentration]/ [time taken] e.

[0.31 - 0.17] / [60-30] = 0.00467 mol L-1 sec-1

(ii) the pseudo first-order rate constant can be calculated by K = (2.303/t) log (Ci/Ct)

where K is Rate constant,

t is time taken,

Ci is initial concentratio

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Chemistry Ncert Solutions Class 12th 2023

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