4.29 For the decomposition of azoisopropane to hexane and nitrogen at 543 K, the following data are obtained. 

Calculate the rate constant.

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8 months ago

4.29 When t = 0, the total partial pressure is P0 = 35.0 mm of Hg

When time t = t, the total partial pressure is Pt = P0 + p

P0-p = Pt-2p, but by the above equation, we know p = Pt-P0 Hence, P0-p = Pt-2 ( Pt-P0)

Thus, P0-p = 2P0 – Pt

We know that time

t= 2.303/K log R0 / R

Where, k- rate constant

[R]° -In

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