A copper complex crystallizing in a CCP lattice with a cell edge of 0.4518 nm has been revelaed by employing X-ray diffraction studies. The density of a copper complex is found to be 7.26 g cm-3. The molar mass of copper complex is___________ g mol-1. (Nearest integer)

[Given : NA = 6.022 * 1023 mol-1]

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6 months ago

Density, ρ = 7 . 6 2 g c m 3  

Cell edge, a = 0.4518nm = 0.458 * 10-7 cm

Effective number of atoms, Z = 4 for CCP.

Using ; ρ = Z * A N A * a 3  

ρ = 4 * A 6 . 0 2 2 * 1 0 2 3 * ( 0 . 4 5 8 * 1 0 7 ) 3              

7 . 6 2 = 4 * A 6 . 0 2 2 * ( 0 . 4 5 1 8 ) 3 * 1 0 2              

A = 105.79 g/mol

Ans. is 106 (the nearest integers)

 

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Chemistry Ncert Solutions Class 12th 2023

Chemistry Ncert Solutions Class 12th 2023

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