Amongst the following which one will have maximum lone pair -lone pair' electron repulsions?

PF₅, PCl₅, PBr₅, Fe (CO)₅ Þ Trigonal bipyramidal

BrF₅ Þ Square pyramidal

[PtCl₄]^2– Þ Square planar

SF₆ Þ Octahedral

During the electrolysis of dilute H₂SO₄

$2H_{2}S{O}_4\stackrel{\left(1\right)electrolysis}{\to }2HS{O}_4^{-}+2H^{+}$  

$H_2{S}_2{O}_8+2H_{2}O\stackrel{hydrolysis}{\to }2H_{2}S{O}_4+\underset{\left(A\right)}{H_2{O}_2}$  

$2H^{+}+2e\to H_2\uparrow$  

In the solid form of  $H_2{O}_2$ dihedral angle is equal to 90.2°.

Total number of electron in Ti = 22
Total number of electron in Ti? = 22 – 4 = 18 So EAN value of Ti = 18 + 12 + 4 = 34