Correct electronic configuration of cobalt in complex cation [ C o ( N H 3 ) 6 ] 3 +  is (Atomic No. of Co is 27)

Option 1 - <p><span class="mathml" contenteditable="false"> <math> <mrow> <msubsup> <mrow> <mi>t</mi> </mrow> <mrow> <mn>2</mn> <mi>g</mi> </mrow> <mrow> <mn>4</mn> </mrow> </msubsup> <msubsup> <mrow> <mi>e</mi> </mrow> <mrow> <mi>g</mi> </mrow> <mrow> <mn>2</mn> </mrow> </msubsup> </mrow> </math> </span></p>
Option 2 - <p><span class="mathml" contenteditable="false"> <math> <mrow> <msubsup> <mrow> <mi>t</mi> </mrow> <mrow> <mn>2</mn> <mi>g</mi> </mrow> <mrow> <mn>4</mn> </mrow> </msubsup> <msubsup> <mrow> <mi>e</mi> </mrow> <mrow> <mi>g</mi> </mrow> <mrow> <mn>1</mn> </mrow> </msubsup> </mrow> </math> </span></p>
Option 3 - <p><span class="mathml" contenteditable="false"> <math> <mrow> <msubsup> <mrow> <mi>t</mi> </mrow> <mrow> <mn>2</mn> <mi>g</mi> </mrow> <mrow> <mn>6</mn> </mrow> </msubsup> <msubsup> <mrow> <mi>e</mi> </mrow> <mrow> <mi>g</mi> </mrow> <mrow> <mn>0</mn> </mrow> </msubsup> </mrow> </math> </span></p>
Option 4 - <p><span class="mathml" contenteditable="false"> <math> <mrow> <msubsup> <mrow> <mi>t</mi> </mrow> <mrow> <mn>2</mn> <mi>g</mi> </mrow> <mrow> <mn>5</mn> </mrow> </msubsup> <msubsup> <mrow> <mi>e</mi> </mrow> <mrow> <mi>g</mi> </mrow> <mrow> <mn>1</mn> </mrow> </msubsup> </mrow> </math> </span></p>
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4 months ago
Correct Option - 3
Detailed Solution:

  [ C o ( N H 3 ) 6 ] 3 + , N H 3 becomes strong ligand due to +3 oxidation state of cobalt ion. Hence electronic configuration of CO3+ is t 2 g 6 e g 0  

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Chemistry Coordination Compounds 2025

Chemistry Coordination Compounds 2025

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