Cu(s) + Sn2+(0.001M) Cu2+ (0.01M) + Sn(s)

The Gibbs free energy change for the above reaction at 298 K is x * 101 KJmol1. The value of x is __________. (nearest integer)

[Given :  0.34V;  = 0.14V; F = 96500 Cmol1]

2 Views|Posted 5 months ago
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1 Answer
R
5 months ago

cell reaction is ;

              C u ( s ) + S n ( a q ) 2 + C u ( a q ) + + + S n ( s )  

              Q = [ C u + + ] [ S n + + ] = 0 . 0 1 0 . 0 0 1 a n d n = 2  

              E c e l l = E c e l l o 0 . 0 5 9 2 l o g 0 . 0 1 0 . 0 0 1  

              = 0 . 4 8 0 . 0 5 9 2 l o g 1 0 = 0 . 5 0 9  

              = 9 8 3 . 3 3 * 1 0 1 K J / m o l e  

              Nearest integer = 983

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Chemistry Electrochemistry 2025

Chemistry Electrochemistry 2025

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