EᶱCell for some half-cell reactions are given below. On the basis of these mark the correct answer
(a) ; EᶱCell =0.00V
(b) ; EᶱCell =1.23V
(c) ; EᶱCell =1.96V
(i) In dilute sulphuric acid solution, hydrogen will be reduced at the cathode.
(ii) In concentrated sulphuric acid solution, water will be oxidized at the anode.
(iii) In dilute sulphuric acid solution, water will be oxidized at the anode.
(iv) In dilute sulphuric acid solution, SO42− ion will be oxidized to tetrathionate ion at the anode
EᶱCell for some half-cell reactions are given below. On the basis of these mark the correct answer
(a) ; EᶱCell =0.00V
(b) ; EᶱCell =1.23V
(c) ; EᶱCell =1.96V
(i) In dilute sulphuric acid solution, hydrogen will be reduced at the cathode.
(ii) In concentrated sulphuric acid solution, water will be oxidized at the anode.
(iii) In dilute sulphuric acid solution, water will be oxidized at the anode.
(iv) In dilute sulphuric acid solution, SO42− ion will be oxidized to tetrathionate ion at the anode
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1 Answer
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This is a Multiple Choice Questions as classified in NCERT Exemplar
Ans: Correct Option: Option (i, iii)
In the electrolysis of sulphuric acid, the following reactions occur
2SO42− (aq)→S2O82− (aq) + 2e− E? Cell =1.96V
2H2O (l)→O2 (g)+4H+ (aq) + 4e− E? Cell =1.23V
The reaction will lower the value of E? Cell is preferred at anode so the second reaction is feasible.
H+ + e− → H2 E? Cell = 0.00V
At the cathode, reduction of water occurs. Therefore, in dilute sulphuric acid solution, hydrogen will be reduced at the cathode.
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