Find the emf of the cell in which the following reaction takes place at 298 K
Ni(s) + 2Ag⁺(0.001M) → Ni²⁺(0.001M) + 2Ag(s)
(Given that E°cell = 1.05 V, 2.303RT/F = 0.059 at 298 K)

Option 1 -

1.0385 V

Option 2 -

1.385 V

Option 3 -

0.9615 V

Option 4 -

1.05 V

0 3 Views | Posted a month ago
Asked by Shiksha User

  • 1 Answer

  • V

    Answered by

    Vishal Baghel | Contributor-Level 10

    a month ago
    Correct Option - 3


    Detailed Solution:

    Ecell = 1.05 - (0.059 / 2) log ( [Ni²? ] / [Ag? ]²)
    = 1.05 - (0.059 / 2) log ( [10? ³] / [10? ³]²)
    = 1.05 - (0.059 × 3) / 2 = 1.05 - 0.0885 = 0.9615 volt
    There is a misprint in the question. The E? cell is incorrectly given as 10.5 V. This should have been 1.05 volt.

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A
alok kumar singh

Ecell = 0 – log2

= – 0.03 (0.3)

 = – 0.009

 = – 9 * 10–3 V

x = 9

V
Vishal Baghel

H2 (g) + Cu2+ (aq)  2H+ (aq) + Cu (s)

  E c e l l = E c e l l 0 2 . 3 0 3 R T n f l o g Q

0.31 = 0.34 - 0 . 0 6 2 l o g [ H + ] C u 2 +  

  [ C u 2 + ] = 1 0 7 ( ? [ H + ] = 1 0 3 )

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A
alok kumar singh

H2 (g) + Cu2+ (aq)  2H+ (aq) + Cu (s)

E c e l l = E c e l l 0 2 . 3 0 3 R T n f l o g Q  

0.31 = 0.34 -  0 . 0 6 2 l o g [ H + ] C u 2 +  

[ C u 2 + ] = 1 0 7 ( ? [ H + ] = 1 0 3 )  

x = 7

A
alok kumar singh

E_cell = E? _cell - (0.059/2)log { [Cu²? ]/ [Ag? ]²}
E? = E? _cell - (0.059/2)log [0.1/ (0.01)²] = 0.3095
E? _cell = 0.3095 + 0.0885 V
E? _cell = 0.398

Again, E? = E? _cell - (0.059/2)log [10? ²/ (10? ³)²]
E? = 0.398 - (0.059/2) x 4 V

E? = 0.28 V
E? = 28 x 10? ² V

R
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Benzyl amine (0.1 mole) reacts with 3 equivalents of CH? Br to form Benzyl trimethyl ammonium bromide.

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