For the given reactions

Sn2 + 2e- ® Sn

Sn4 + 4e- ® Sn

The electrode potentials are ; E S n 2 + / S n o = -0.140V and E S n 4 + / S n o = 0 . 0 1 0 V . The magnitude of standard electrode potential for Sn4+ / Sn2+ i.e. E S n 4 + / S n 2 + o  is ___________ * 10-2 V. (Nearest integer)

10 Views|Posted 6 months ago
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A
6 months ago

E S n 2 + / S n 0 = 0 . 1 4 0 V = E 2 0

E S n 4 + / S n 0 = + 0 . 0 1 0 V = E 3 0

Here, Δ G 3 0 = Δ G 1 0 + Δ G 2 0

4 F E 3 0 = 2 F E 1 0 2 F E 2 0

E 3 0 = E 1 0 + E 2 0 2

+ 0 . 0 1 0 = E 1 0 + ( 0 . 1 4 0 ) 2

E 1 0 = E S n 4 + / S n 2 + 0 = + 0 . 1 6

= 16 * 10-2 V

 

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Chemistry NCERT Exemplar Solutions Class 12th Chapter Three 2025

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