Select the INCORRECT statement:

Option 1 - At Boyle’s temperature a real gas behaves like an ideal gas irrespective of pressure.

Option 2 - At Boyle’s temperature; z = 1 +  <math> <mrow> <mfrac> <mrow> <msup> <mrow> <mi>b</mi> </mrow> <mrow> <mn>2</mn> </mrow> </msup> </mrow> <mrow> <msub> <mrow> <mi>V</mi> </mrow> <mrow> <mi>m</mi> </mrow> </msub> <mrow> <mo>(</mo> <mrow> <msub> <mrow> <mi>V</mi> </mrow> <mrow> <mi>m</mi> </mrow> </msub> <mo>−</mo> <mi>b</mi> </mrow> <mo>)</mo> </mrow> </mrow> </mfrac> </mrow> </math>

Option 3 - On increasing the temperature four times, collision frequency (Z1) becomes double at constant volume.

Option 4 - At high pressure Vander Waals constant ‘b’ dominated over ‘a’.

1 Views|Posted 5 months ago

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Answered by

Alok Kumar Singh | Contributor-Level 10

5 months ago

Correct Option - 1

Detailed Solution:

At Boyle's Temperature ; gas behaves ideally for a range of pressure.

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