The molecule in which hybrid MOs involve only one d-orbital of the central atom is :

<p><strong>Sol.</strong>&nbsp;<math><mrow></mrow><mi mathvariant="normal">U</mi></math>&nbsp;and&nbsp;<math><mi mathvariant="normal">H</mi></math>&nbsp;are temperature dependent</p><p><math><msub><mrow><mrow><mi mathvariant="normal">C</mi></mrow></mrow><mrow><mrow><mi mathvariant="normal">P</mi><mo>, </mo><mi mathvariant="normal">m</mi></mrow></mrow></msub><mo>-</mo><msub><mrow><mrow><mi mathvariant="normal">C</mi></mrow></mrow><mrow><mrow><mi mathvariant="normal">V</mi><mo>, </mo><mi mathvariant="normal">m</mi></mrow></mrow></msub><mo>=</mo><mi mathvariant="normal">R</mi></math>&nbsp; (for 1 mole of ideal gas)</p><p><math><mi mathvariant="normal">d</mi><mi mathvariant="normal">U</mi><mo>=</mo><msub><mrow><mrow><mi mathvariant="normal">C</mi></mrow></mrow><mrow><mrow><mi mathvariant="normal">V</mi></mrow></mrow></msub><mi mathvariant="normal">d</mi><mi mathvariant="normal">t</mi></math></p>

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