The type of hybridisation and magnetic property of the complex [MnCl?]³?, respectively, are:
The type of hybridisation and magnetic property of the complex [MnCl?]³?, respectively, are:
[MnCl? ]³?
Mn (25) → [Ar] 4s²3d?
Cl? → weak ligand
Mn³? → 3d? i.e. t? g³, eg¹
Hybridization → sp³d² and paramagnetic
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x = 5
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3d => 4d => 5d CFSE increases for the same ligands.
Factual
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σ bonded organometallic compound ⇒ M – C
σ-bond
and in π – bonded organo metallic compound
M – C
π bond
In ferrocene, there is π-bond
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Chemistry Coordination Compounds 2025
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