What is the nature of bonding in NiCO4?
What is the nature of bonding in NiCO4?
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1 Answer
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The nature of bonding in Ni (CO)? includes synergic bonding. The synergic bonding in metal carbonyls like nickel tetracarbonyl is due to two-way interaction of metal and carbonyl ligand electron density donation.
The synergic bonding is best explained thorugh Molecular Orbital Theory (MOT), which explains the donation of electron density from the filled d-orbitals of nickel (Ni) into the antibonding? * orbitals of the carbon monoxide (CO) ligand.
The synergic bonding can be described as a combination of? -bond formation due to donation of lone pair to metal center, and? back-bond formation due to donation of lone pair to CO ligand.
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