When liquid 'A' is treated with a freshly prepared ammoniacal silver nitrate solution, it gives bright silver mirror. The liquid forms a white crystalline solid on treatment with sodium hydrogensulphite. Liquid 'B' also forms a white crystalline solid with sodium hydrogensulphite but it does not give test with ammoniacal silver nitrate. Which of the two liquids is aldehyde? Write the chemical equations of these reactions also. 

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7 months ago

This is a Long Answer Type Questions as classified in NCERT Exemplar

Ans: Liquid 'A' reduces ammoniacal silver nitrate and 'B' is a ketone which forms white crystalline solid on treatment with hydrogen sulphite

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ΔG° = –RT * 2.303 log K

–nFE° = +RT * 2.303 log K

2 * 96500 * 0.295 = 8.314 * 298 * 2.303 log10 K

10 = log10 K = 1010

It has chiral centre and differently di substituted double bonded carbon atoms.

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Chemistry NCERT Exemplar Solutions Class 12th Chapter Twelve 2025

Chemistry NCERT Exemplar Solutions Class 12th Chapter Twelve 2025

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