1.20 What type of stoichiometric defect is shown by: (i) ZnS (ii) AgBr
1.20 What type of stoichiometric defect is shown by: (i) ZnS (ii) AgBr
1.20 ZnS shows Frenkel Defect.
AgBr shows Frenkel Defect and Schottky Defect. Frenkel Defect: It is a kind of defect in crystalline solids in which atoms are displaced from their lattice position
to interstitial site creating vacancy at the lattice point. It usually occurs in ionic solid with large d
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ΔG° = –RT * 2.303 log K
–nFE° = +RT * 2.303 log K
2 * 96500 * 0.295 = 8.314 * 298 * 2.303 log10 K
10 = log10 K = 1010
It has chiral centre and differently di substituted double bonded carbon atoms.
For FCC lattice
Packing efficiency = 
CsCl has BCC structure in which Cl– is present at corners of cube and Cs+ at body centre
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