1.34 Calculate the efficiency of packing in case of a metal crystal for (i) Simple cubic (ii) Body-centred cubic (iii) Face-centred cubic (with the assumptions that atoms are touching each other). 

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    alok kumar singh | Contributor-Level 10

    4 months ago

    1.34 (i) The efficiency of packing in case of simple cubic unit cell is given below: 
    A simple cubic unit cell contains one atom per unit cell.
    Also, a=2r, where a is the edge length and r is the radius of atom. Total volume of unit cell = a3
    Packing efficiency = Volume of one sphere / Total volume of unit cell × 100

    Packing Effieciency = 4/3πr3 / 8r3 X 100 = 52.4%

    (ii) The efficiency of packing in case of body-centred cubic unit cell is given below:
    A body-centred cubic unit cell containstwo atoms per unit cell.
    Also, √3a = 4r,where a isthe edge length and r isthe radius of atom.
    Total volume of unit cell = a3
    Packing effic

    ...more

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ΔG° = –RT * 2.303 log K

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Kindly go through the solution

 

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CsCl has BCC structure in which Cl is present at corners of cube and Cs+ at body centre

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