11.30. A certain salt X, gives the following results.
(i) Its aqueous solution is alkaline to litmus.
(ii) It swells up to a glassy material Y on strong heating.
(iii) When conc.H2SO4is added to a hot solution of X, white crystal of an acid Z separates out.

Write equations for all the above reactions and identify X, Y and Z. (Advance)

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9 months ago

The compounds X, Y and Z are borax, sodium metaborate + boric anhydride and boric acid respectively.

When borax is heated, it first swells and then forms a transparent glass like bead of sodium meta borate and boric anhydride.

Na2B4O7 à2NaBO2+B2O3+10H2O

(Borax)       (sodium metaborate) (Boric anhydrid

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