12.33. A sample of 0.50 g of an organic compound was treated according to Kjeldahl's method. The ammonia evolved was absorbed in 50 ml of 0.5M H2SO4. The residual acid required 60 ml of 0.5 M solution of NaOH for neutralization. Find the percentage composition of nitrogen in the compound.
12.33. A sample of 0.50 g of an organic compound was treated according to Kjeldahl's method. The ammonia evolved was absorbed in 50 ml of 0.5M H2SO4. The residual acid required 60 ml of 0.5 M solution of NaOH for neutralization. Find the percentage composition of nitrogen in the compound.
Step I: Calculation of volume of unused acid i.e. V2 =?
V1 = Volume of NAOH solution required = 60 cm3
N1 = Normality of NaOH solution = ½ N
N2 = Normality of H2SO4 = 1N
Applying N1V1 = N2V2
½ N x 60 cm3 = 1N x V2
Or V2 = 30 cm3
Step II: calculation of volume of acid used
Volume of acid added = 50 cm3
Volu
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Chemistry Ncert Solutions Class 11th 2023
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