Class 11th Redox Reactions Redox Reactions Chemistry Ncert Solutions Chemistry Class 11th

8.14. Consider the reactions:

Why does the same reductant, thiosulphate react differently with iodine and bromine?

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Vishal Baghel | Contributor-Level 10

10 months ago

The average O.N. of S in S₂O₃^2- is +2 while in S₄O₆^2- it is + 2.5. The O.N. of S in SO₄^2- is +6. Since Br₂ is a stronger oxidising agent than I₂, it oxidises S of S₂O₃^2- to a higher oxidation state of +6 and hence forms SO₄^2- ion. I₂, however, being weaker oxidising agent oxidises S of S₂O₃^2- ion to

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How many of these compounds will undergo disproportionation on hydrolysis? CO?, NO?, Cl?, F?, ClO?, Cl?O?, N?O?, SO?, P?O??

$\overset{\overset{+ 4}{{N O}_{2}}}{2} + H_{2} O \to \overset{+ 3}{{H N O}_{2}} + \overset{+ 5}{H N O}_{3}$

$\overset{0}{{C l}_{2}} + H_{2} O \to \overset{- 1}{H C l} + H O C l$

$2 \overset{+ 4}{{C l O}_{2}} + H_{2} O \to \overset{+ 3}{{H C l O}_{2}} + \overset{+ 5}{{H C l O}_{3}}$

$\overset{+ 6}{{C l}_{2}} O_{6} + H_{2} O \to \overset{+ 5}{{H C l O}_{3}} + \overset{+ +^{+}}{{C l O}_{4}}$

40. Best reducing agent is:
(a) He (b) Be (c) Li (d) Al

Kindly go through the solution

(c) Li

37. Which element is considered to have oxidation number of +3 in all its compounds?

(a) Be (b) Li (c) Al (d) Sc

Kindly go through the solution

(c) Al

36. Oxidation number ofS in S₂O₈^-2is

(a) -2 (b) -6 (c) +2 (d) +6

Kindly go through the solution

(d) +6

32. Assertion: Na⁺ ion has an oxidation number of +1, Mg²⁺ ion, +2, Fe³⁺ion, +3, Cl^– ion, –1, O^2– ion, –2; and so on.

Reason: For ions composed of only one atom, the oxidation number is equal to the charge on the ion.

Kindly go through the solution

(a)

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