8.20. What sorts of information can you draw from the following reaction?
(CN)2(g) + 2OH–(aq) → CN–(aq) + CNO–(aq) + H2O(l)
8.20. What sorts of information can you draw from the following reaction?
(CN)2(g) + 2OH–(aq) → CN–(aq) + CNO–(aq) + H2O(l)
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1 Answer
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Let x be the O.N. of C.
O.N. of C in cyanogen, (CN)2 = 2 (x – 3) = 0 or x = +3O.N. of C in cyanide ion, CN- = x – 3 = -1 or x = +2
O.N. of C in cyanate ion, CNO =x-3-2 = -l or x: = +4
The four information about the reaction are:
(i) The reaction involves decomposition of cyanogen, (CN)2 in the alkaline medium to cyanide ion, CN and cyanate ion, CNO–.(ii) The O.N. of C decreases from +3 in (CN)2 to +2 in CN–ion and increases from +3 in (CN)2 to +4 in CNO– ion. Thus, cyanogen is simultaneously reduced to cyanide ion and oxidised to cyanate ion.
(iii) It is an example of a redox reaction in general an
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