8.26 Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with (i) iron(II) ions (ii) SO2 and (iii) oxalic acid? Write the ionic equations for the reactions.

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8.26 Potassium permanganate can be prepared from MnO2. It can be done by fusing the ore with KOH in presence of an oxidizing agent like atmospheric oxygen/KNO3 etc to give green coloured K2MnO4 as the product.

2MnO2 + 4KOH + O2 → 2K2MnO4 + 2H2O

The Product K2MnO4 is extracted with water and then oxidi

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Potassium permanganate in alkaline medium oxidise lodide to lodate.

2 M n O 4 + H 2 O + I Θ 2 M n O 2 + 2 O H Θ + I O 3 Θ ( A )            

Compound A is  . Therefore, oxidation state of 1is + 5.

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KMnO4 decomposes upon heating at 513 K and forms K2MnO4 and MnO2.

2KMnO4  K2MnO4 + O2 + MnO2

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Chemistry Ncert Solutions Class 12th 2023

Chemistry Ncert Solutions Class 12th 2023

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