8.26. Using the standard electrode potentials given in Table 8.1, predict if the reaction between the following is feasible:
(a) Fe3+(aq) and I-(aq) (b) Ag+ (aq) and Cu(s)
(c) Fe3+(aq) and Cu(s) (d) Ag(s) and Fe3+(aq)
(e) Br2 (aq) and Fe3+ (aq). (Advance)
8.26. Using the standard electrode potentials given in Table 8.1, predict if the reaction between the following is feasible:
(a) Fe3+(aq) and I-(aq) (b) Ag+ (aq) and Cu(s)
(c) Fe3+(aq) and Cu(s) (d) Ag(s) and Fe3+(aq)
(e) Br2 (aq) and Fe3+ (aq). (Advance)
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1 Answer
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(i) When emf is positive, the reaction is feasible.
Eo? cell = Eo? Fe? −Eo? I2? =0.77−0.54=0.23V
Reaction is feasible.
(ii) Eo? cell? =Eo? Ag? −Eo? Cu? =0.80−0.34=0.46V
Reaction is feasible.
(iii) Eo? cell? =Eo? Fe? −Eo? Cu? =0.77−0.34 =0.43 V
Reaction is feasible.
(iv) Eo? cell? =Eo? Fe? −Eo? Ag? =0.77−0.80=−0.03 V
Reaction is not feasible.
(v) Eo? cell? =Eo? Br2? ? −EFe? =1.09−0.77=0.32 V
Reaction is feasible.
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