8.30. Depict the galvanic cell in which the reaction, Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s)
takes place. Further show:
(i) Which of the electrode is negatively charged.
(ii) The carriers of current in the cell and
(iii) Individual reaction at each electrode. (Advance)
8.30. Depict the galvanic cell in which the reaction, Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s)
takes place. Further show:
(i) Which of the electrode is negatively charged.
(ii) The carriers of current in the cell and
(iii) Individual reaction at each electrode. (Advance)
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1 Answer
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The given redox reaction can be depicted as
Zn (s) + 2Ag+ (aq) → Zn2+ (aq) + 2Ag (s)
Since Zn gets oxidised to Zn2+ ions, and Ag+ gets reduced to Ag metal, therefore,Oxidation occurs at the zinc electrode and reduction occurs at the silver electrode. Thus, galvanic cell corresponding to the above redox reaction may be depicted as:
Zn|Zn2+ (aq) | Ag+ (aq) | Ag
(i) Zinc electrode is negatively charged because oxidation occurs at the zinc electrode (i.e. electrons accumlulate on the zinc electrode)
(ii) The ions carry current. The electrons flow from Zn to Ag electrode while the current flows from Ag to Zn electrode.
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