8.8. While sulphur dioxide and hydrogen peroxide can act as an oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?
8.8. While sulphur dioxide and hydrogen peroxide can act as an oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why?
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1 Answer
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(i) In SO2, O.N. of S is +4. In principle, S can have a minimum O.N. of -2 and maximum of +6. Therefore, S in SO2 can either decrease or increase its O.N. and hence can act both as an oxidising as well as a reducing agent.
(ii) In H2O2, the O.N. of O is -1. In principle, O can have a minimum O.N. of -2 and maximum of zero (+1 is possible in O2F2 and +2 in OF2). Therefore, O in H2O2 can either decrease its O.N. from -1 to -2 or can increase its O.N. from -1 to zero. Therefore, H2O2 acts both as an oxidising as well as a reducing agent.
(iii) In O3, the O.N. of O is zero. It can only decrease its O.N. from zero to -1 or -
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