9.17 Using IUPAC norms write the systematic names of the following:
(i) [Co(NH3)6]Cl3
(ii) [Pt(NH3)2Cl(NH2CH3)]Cl
(iii) [Ti(H2O)6] 3+
(iv) [Co(NH3)4Cl(NO2)]Cl
(v) [Mn(H2O)6] 2+
(vi) [NiCl4] 2–
(vii) [Ni(NH3)6]Cl2
(viii) [Co(en)3] 3+
(ix) [Ni(CO)4]
9.17 Using IUPAC norms write the systematic names of the following:
(i) [Co(NH3)6]Cl3
(ii) [Pt(NH3)2Cl(NH2CH3)]Cl
(iii) [Ti(H2O)6] 3+
(iv) [Co(NH3)4Cl(NO2)]Cl
(v) [Mn(H2O)6] 2+
(vi) [NiCl4] 2–
(vii) [Ni(NH3)6]Cl2
(viii) [Co(en)3] 3+
(ix) [Ni(CO)4]
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1 Answer
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(i) Starting with cation, the complex ion contains six ammonia molecules with cobalt in + 3 oxidation The name of compound: [Co (NH3)6]Cl3 is hexaamminecobalt (III) chloride.
(ii) The complex ion is cation, so there are 2 ammonia molecules, one chloride ion and methyammine molecule qith platinum in + 2 state. Going in alphabetical order, the name of compound: [Pt (NH3)2Cl (NH2CH3)]Cl is diamminechloridomethylammineplatinum (II)
(iii) It is a complex cation with six water molecules and titanium atom in + 3 state. The name of the compound: [Ti (H2O)6]3+ is hexaaquatitanium (III) ion
(iv) The complex ion is cation with
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