A 2.0g sample containing MnO2 is treated with HCl liberating Cl2. The Cl2 gas is passed into a solution of Kl and 60.0mL of 0.1M Na2S2O3 is required to titrate the liberated iodine. The percentage of MnO2 in the sample is_______. (Nearest integer)
[Atomic masses (in u) Mn = 55; Cl = 35.5; O = 16, I = 127, Na = 23, K = 39, S = 32]
A 2.0g sample containing MnO2 is treated with HCl liberating Cl2. The Cl2 gas is passed into a solution of Kl and 60.0mL of 0.1M Na2S2O3 is required to titrate the liberated iodine. The percentage of MnO2 in the sample is_______. (Nearest integer)
[Atomic masses (in u) Mn = 55; Cl = 35.5; O = 16, I = 127, Na = 23, K = 39, S = 32]
Here, meq of MnO2 = meq of Na2S4O6
Mass of MnO2 in sample = 0.261 g
Percentage of MnO2 in sample =
= 13.05%
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CH3COOH + NaOH → CH3COONa + H2O
ΔH = –50.6 kJ/mol
NaOH + SA [HCl] → NaCl + H2O
ΔH = –55.9 kJ/mol
the value of ΔH for ionisation of CH3COOH
⇒ ΔH = +55.9 – 50.6
5.3 kJ/mol
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Chemistry NCERT Exemplar Solutions Class 12th Chapter Seven 2025
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