An organic compound with the molecular formula C9H10O forms 2,4-DNP derivative, reduces Tollens' reagent and undergoes Cannizzaro reaction. On vigorous oxidation, it gives 1,2-benzenedicarboxylic acid. Identify the compound.
An organic compound with the molecular formula C9H10O forms 2,4-DNP derivative, reduces Tollens' reagent and undergoes Cannizzaro reaction. On vigorous oxidation, it gives 1,2-benzenedicarboxylic acid. Identify the compound.
Since the given compound with molecular formula C9H10O form a 2,4-DNP derivative and reduce Tollen's reagent, it must be an aldehyde. Since it undergoes cannizzaro reaction, therefore CHO group is directly attached to the benzene ring.
Since on vigorous oxidation, it gives 1,2-benzene dicarboxylic ac
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CH3—CH2—CHO does not undergo Cannizzaro reaction because it has α-hydrogen.
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Chemistry Aldehydes, Ketones and Carboxylic Acids 2021
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