Given below are two statements : one is labeled as Assertion (A) and the other is labeled as

Reason (R).

Assertion (A): Experimental reaction of CH3Cl with aniline and anhydrous AlCl3 does not give O and P-methylaniline.

Reason (R) : The -NH2 groups of aniline becomes deactivating because of salt formation with anhydrous AlCl3 and hence yields m-methyl aniline as the product.

In the light of the above statements, choose the most appropriate  answer from the options given below:

Option 1 -

Both (A) and (B) are true and (R) is the correct explanation of (A).

Option 2 -

Both (A) and (B) are true and (R) is the correct explanation of (A).

Option 3 -

(A) is true, but (R) is false.

Option 4 -

(A) is true, but (R) is false.

0 2 Views | Posted 2 months ago
Asked by Shiksha User

  • 1 Answer

  • V

    Answered by

    Vishal Baghel | Contributor-Level 10

    2 months ago
    Correct Option - 3


    Detailed Solution:

    Aniline makes adduct with AlCl3 and thus gets deactivated for electrophilic aromatic substitution and do not react with CH3-Cl

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