In Lassaigne's extract of an organic compound, both nitrogen and sulphur are present, which gives blood red colour with Fe3+ due to the formation of

Option 1 -

[Fe(SCN)]²⁺

Option 2 -

Fe₄[Fe(CN)₆]₃·xH₂O

Option 3 -

NaSCN

Option 4 -

[Fe(CN)₅NOS]⁴⁻

0 2 Views | Posted a month ago
Asked by Shiksha User

  • 1 Answer

  • V

    Answered by

    Vishal Baghel | Contributor-Level 10

    a month ago
    Correct Option - 1


    Detailed Solution:

    In case, nitrogen and sulphur both are present in an organic compound, sodium thiocyanate is formed.
    Na + C + N + S → NaSCN
    Which further reacts as:
    Fe³? + SCN? → [Fe (SCN)]²?
    (Blood red color)

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