In reaction with Cl2 , phosphorus forms two types of halides ‘A’ and ‘B’. Halide A is yellowish-white powder but halide ‘B’ is colourless oily liquid. Identify A and B and write the formulas of their hydrolysis products.
In reaction with Cl2 , phosphorus forms two types of halides ‘A’ and ‘B’. Halide A is yellowish-white powder but halide ‘B’ is colourless oily liquid. Identify A and B and write the formulas of their hydrolysis products.
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1 Answer
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This is a short answer type question as classified in NCERT Exemplar
A is PCl5 (yellowish white powder)
P4 + 10Cl2→4PCl5
B is PCl3 (colourless oily liquid)
Hydrolysis of the following product
PCl3+3H2O→H3PO3+3HCl
PCl5+4H2O→H3PO4+5HCl
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