This is a multiple choice answer as classified in NCERT Exemplar
(III) b < c < a
The reaction will proceed by SN1 mechanism to form the carbocation intermediate, more the stability of carbocation more will be the reactivity of the given compound with HBr/HC1.
-NO2 group is an electron withdrawing group and due to the -M effect, increases the stability of carbocation. Cl group at para position shows + M effect due to it, carbocation is least stable and hence, the compound (c) is the least reactive.
<p><span data-teams="true">This is a multiple choice answer as classified in NCERT Exemplar</span></p><p> (III) b < c < a </p><p>The reaction will proceed by SN<sup>1</sup> mechanism to form the carbocation intermediate, more the stability of carbocation more will be the reactivity of the given compound with HBr/HC1.</p><p>-NO<sub>2</sub> group is an electron withdrawing group and due to the -M effect, increases the stability of carbocation. Cl group at para position shows + M effect due to it, carbocation is least stable and hence, the compound (c) is the least reactive.</p>
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