The quantum numbers of six electrons are given below. Arrange them in order of increasing energies. List if any of these combination(s) has/have the same energy
(i) n = 4, l = 2, ml = -2, ms = -1/2
(ii) n = 3, l = 2, ml = 1, ms = +1/2
(iii) n = 4, l = 1, ml = 0, ms = +1/2
(iv) n = 3, l = 2, ml = -2, ms = -111
(v) n = 3, l = l, ml = -1, ms = +1/2
(vi) n = 4, l = 1, ml = 0, ms = +1/2
The quantum numbers of six electrons are given below. Arrange them in order of increasing energies. List if any of these combination(s) has/have the same energy
(i) n = 4, l = 2, ml = -2, ms = -1/2
(ii) n = 3, l = 2, ml = 1, ms = +1/2
(iii) n = 4, l = 1, ml = 0, ms = +1/2
(iv) n = 3, l = 2, ml = -2, ms = -111
(v) n = 3, l = l, ml = -1, ms = +1/2
(vi) n = 4, l = 1, ml = 0, ms = +1/2
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1 Answer
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The electrons may be assigned to the following orbitals :
(i) 4d
(ii) 3d
(iii) 4p
(iv) 3d
(v) 3p
(vi) 4p.
The increasing order of energy is :
(v) < (ii) = (iv) < (vi) = (iii) < (i)
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Kindly go through the answers
(7.00)
Kindly consider the following Image
In 4d orbital, n = 4 and
Radial nodes =
Radial nodes = 4 – 2 – 1 = 1
And angular nodes,
Here, number of unpaired electrons, n = 1
Spin only moment ;
= 173 × 10-2 B.M
=
= (At constant pressure)
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