The reaction that occurs in a breath analyser, a device used to determine the alcohol level in a person's blood stream is

2 K 2 C r 2 O 7 + 8 H 2 S O 4 + 3 C 2 H 6 O 2 C r 2 ( S O 4 ) 3 + 3 C 2 H 4 O 2 + 2 K 2 S O 4 + 1 1 H 2 O

If the rate of appearance of Cr2(SO4)3 is 2.67 mol min-1 at a particular time, the rate of disappearance of C2H6O at the same time is________mol min-1. (Nearest integer)

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7 months ago

2 K 2 C r 2 O 7 + 8 H 2 S O 4 + 3 C 2 H 6 O 2 C r 2 ( S O 4 ) 3 + 3 C 2 H 4 O 2 + 2 K 2 S O 4 + 1 1 H 2 O

Given that, rate of appearance of Cr2(SO4)3 = + d [ C r 2 ( S O 4 ) 3 ] d t = 2 . 6 7 m o l e / m i n  

LHS                                                                 RHS

( R a t e o f d i s a p p e a r a n c e o f C 2 H 6 O 3 ) = ( R a t e o f a p p e a r a n c e o f C r 2 ( S O 4 ) 3 2 )            

Rate of disappearance of C2H6O = 2 . 6 7 * 3 2 m o l / m i n  

Rate of disappearance of C2H6O = 4.005 mol /min

Ans. = 4 (nearest integer)

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Chemistry Redox Reactions 2025

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