The variation of vapour pressure of different liquids with temperature is shown in Fig. 5.6.

i. Calculate graphically boiling points of liquids A and B.
ii. If we take liquid C in a closed vessel and heat it continuously. At what temperature will it boil?
The variation of vapour pressure of different liquids with temperature is shown in Fig. 5.6.

i. Calculate graphically boiling points of liquids A and B.
ii. If we take liquid C in a closed vessel and heat it continuously. At what temperature will it boil?
This is a long answer type question as classified in NCERT Exemplar
i. The boiling points of liquid A is approximately 315 K and of liquid B is approximately 345 K (shown below graphically).

ii. Liquid C in a closed vessel will not boil as the pressure keeps on increasing.
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CH3COOH + NaOH → CH3COONa + H2O
ΔH = –50.6 kJ/mol
NaOH + SA [HCl] → NaCl + H2O
ΔH = –55.9 kJ/mol
the value of ΔH for ionisation of CH3COOH
⇒ ΔH = +55.9 – 50.6
5.3 kJ/mol
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Chemistry NCERT Exemplar Solutions Class 11th Chapter Five 2025
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