Thermodynamic feasibility of the reaction alone cannot decide the rate of the reaction. Explain with the help of one example
Thermodynamic feasibility of the reaction alone cannot decide the rate of the reaction. Explain with the help of one example
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1 Answer
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This is a Short Answer Type Question as classified in NCERT Exemplar
Thermodynamic feasibility is determined by ΔG factors. So, while the conversion of diamond to graphite is thermodynamically viable, the reaction is sluggish and has a high activation energy.
Gibb's free energy is ΔG
ΔG =RtlnkΔGP, T o
at constant pressure and temperature should be negative or less than 0.
For example, Diamond to be converted to Graphite
ΔG=−ve
It is theoretically conceivable, but the rate is extremely slow, and the activation energy is extremely high. The energy required to transform diamond to grap
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