Three moles of AgCl get precipitated when one mole of an octahedral co-ordination compound with empirical formula CrCl?·3NH?·3H?O reacts with excess of silver nitrate. The number of chloride ions satisfying the secondary valency of the metal ion is ______.
Three moles of AgCl get precipitated when one mole of an octahedral co-ordination compound with empirical formula CrCl?·3NH?·3H?O reacts with excess of silver nitrate. The number of chloride ions satisfying the secondary valency of the metal ion is ______.
CrCl? ·3NH? ·3H? O gives 3 moles of AgCl precipitate. This means all three Cl? are outside the coordination sphere.
The complex is [Cr (NH? )? (H? O)? ]Cl?
The 3 chloride ions satisfy only primary valency.
secondary valency satisfied by chloride ion = 0
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ΔG° = –RT * 2.303 log K
–nFE° = +RT * 2.303 log K
2 * 96500 * 0.295 = 8.314 * 298 * 2.303 log10 K
10 = log10 K = 1010
It has chiral centre and differently di substituted double bonded carbon atoms.
Rate of ESR ∝ No. of α – H (Hyperconjugation)
Cr3+ion is a most stable in aqueous solution due to. t2g half filled configuration
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Chemistry Coordination Compounds 2025
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