Two isomers (A) and (B) with molar mass 184 g/mol and elemental composition C, 52.2%; H. 4.9% and Br 42.9% gave benzoic acid and p-bromobenzoic acid respectively on oxidation with KMnO4. Isomer 'A' is optically active and gives a pale yellow precipitate when warmed with alcoholic AgNO3. Isomer 'A' and 'B' are respectively

 

Option 1 - <p>a</p>
Option 2 - <p>b</p>
Option 3 - <p>c</p>
Option 4 - <p>d</p>
7 Views|Posted 8 months ago
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1 Answer
V
8 months ago
Correct Option - 3
Detailed Solution:

Kindly consider the following figure

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ΔG° = –RT * 2.303 log K

–nFE° = +RT * 2.303 log K

2 * 96500 * 0.295 = 8.314 * 298 * 2.303 log10 K

10 = log10 K = 1010

It has chiral centre and differently di substituted double bonded carbon atoms.

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Chemistry Biomolecules 2025

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