What is meant by the following terms? Give an example of the reaction in each case.
(i) Cyanohydrin
(ii) Acetal
(iii) Semicarbazone
(iv) Aldol
(v) Hemiacetal
(vi) Oxime
(vii) Ketal
(vii) Imine
(ix) 2,4-DNP-derivative
(x) Schiff's base
What is meant by the following terms? Give an example of the reaction in each case.
(i) Cyanohydrin
(ii) Acetal
(iii) Semicarbazone
(iv) Aldol
(v) Hemiacetal
(vi) Oxime
(vii) Ketal
(vii) Imine
(ix) 2,4-DNP-derivative
(x) Schiff's base
(i) Cyanohydrin:
Cyanohydrins are those organic compounds having the formula RR“2C (OH)CN, wherever R and R“2 can be alkyl or aryl groups.
Aldehydes and ketones react with compound (KCN) within the presence of excess cyanide (NaCN) as a catalyst to field organic compounds.
(ii) Acetal:
Acetals are gem
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CH3—CH2—CHO does not undergo Cannizzaro reaction because it has α-hydrogen.
Acetaldehyde (CH3CHO) gives positive lodoform test and positive Fehling's solution test
CH3—CH2—CHO does not undergo Cannizzaro reaction because it has α-hydrogen.
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Chemistry Aldehydes, Ketones and Carboxylic Acids 2021
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