Which of the following options are correct for [Fe(CN)6]3 - complex?
A: d2sp3 hybridisation
B: sp3d2 hybridisation
C: Paramagnetic
D: Diamagnetic
Which of the following options are correct for [Fe(CN)6]3 - complex?
A: d2sp3 hybridisation
B: sp3d2 hybridisation
C: Paramagnetic
D: Diamagnetic
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1 Answer
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This is a Multiple Choice Questions as classified in NCERT Exemplar
Ans: Correct option: A and C
For answer at (A) Atomic number of Iron is 26 . In ferricyanide complex, iron is in oxidation state of 3+. The orbitals on the metal atom undergoes d2sp3 hybridizaion and hence the complex has octahedral shape.
Also it can be said that, [Fe (CN)6]3- has one unpaired electron which makes it weakiy paramagnetic. Therefore, option C is also correct.
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