Write the mechanism of the reaction of HI with methoxybenzene.

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    Payal Gupta | Contributor-Level 10

    3 months ago

    This is a long answer type question as classified in NCERT Exemplar

    In case of anisole, methylphenyl oxonium ion, is formed by protonation of ether. The bond between O—CH3 is weaker than the bond between O—C6H5 because the carbon of phenyl group is sp2 hybridised and there is partial double bond character. Therefore, the attack by I- ion breaks O—CH3 bond to form CH3I. Phenols do not react further to give halides because the sp2 hybridised carbon of phenol cannot undergo nucleophilic substitution reaction needed for conversion to the halide.

     

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